Enhanced antibiotic degradation performance of Cd0.5Zn0.5S/Bi2MoO6 S-scheme photocatalyst by carbon dot modification

doi:10.1016/j.jmst.2023.05.009

Abstract

Abstract: S-scheme heterojunction engineering is an effective strategy to attain distinctive photocatalysts. Herein, a carbon dots modulated S-scheme hetero-structured photocatalyst of Cd_0.5Zn_0.5S nanoparticles/Bi₂MoO₆ microspheres/carbon dots (CZCBM), aiming to conquer the photo-corrosion and strengthen the photocatalytic property of Cd_0.5Zn_0.5S, was developed via a facile solvothermal route. Under visible light, the optimal CZCBM-2 affords a 1.8-, 1.5-, or 0.6-time reinforcement in the oxytetracycline degradation rate constant compared to Bi₂MoO_6, Cd_0.5Zn_0.5S or Cd_0.5Zn_0.5S/Bi₂MoO₆, which is credited to the strengthened visible-light response, increased reactive sites, and efficient dissolution of photo-carriers with optimal redox capacity because of the co-effect of carbon dots and S-scheme heterostructure. Significantly, the photo-corrosion of Cd_0.5Zn_0.5S is significantly suppressed and CZCBM-2 affords superior stability and reusability during cycling tests. Besides, CZCBM-2 can be well adapted to various environments. The toxicology appraisement unravels the decreased eco-toxicity of most intermediates compared to oxytetracycline. Lastly, an S-scheme charge transfer mechanism with carbon dots as electron reservoir in CZCBM is deduced, which uncloses that •O₂^- and h⁺ dominantly account for oxytetracycline eradication and detoxification. This study demonstrates the design of unique carbon dots favored S-scheme heterostructures as an effective “Two Birds with One Stone” strategy to achieve high anti-photo-corrosion performance and reinforced photocatalytic performance of sulfides.

Key words: Carbon dots, S-scheme heterojunction, Synergistic effect, Pharmaceuticals and personal care products, (PPCPs), Toxicity analysis, Anti-photocorrosion

Shijie Li, Ruyu Yan, Mingjie Cai, Wei Jiang, Mingyi Zhang, Xin Li. Enhanced antibiotic degradation performance of Cd_0.5Zn_0.5S/Bi₂MoO₆ S-scheme photocatalyst by carbon dot modification[J]. J. Mater. Sci. Technol., 2023, 164: 59-67.

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Enhanced antibiotic degradation performance of Cd_0.5Zn_0.5S/Bi₂MoO₆ S-scheme photocatalyst by carbon dot modification

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